How does wall slippage affect hydrodynamic dispersion?

Abstract

How hydrodynamic dispersion is affected by wall slip remains to be fully understood. An attempt is made in this article looking into this issue for dispersion in some elementary pressure-driven flows. Both the long-time Taylor-Aris dispersion and the early-phase convection-dominated dispersion are investigated, analytically and numerically, respectively. The mean and the variance of the residence time distribution are also examined. In the basic case where the walls of a parallel-plate channel have equal slip lengths, the slip is in general to reduce the spread of a solute cloud in a finite channel by either increasing the convection speed or decreasing the dispersivity. However, the decreasing effect of slip on dispersion can be diminished or even reversed by unequal slip lengths and/or phase exchange with the wall. The convection-dominated regime is investigated, following a recently proposed transport-based method, to determine how the mean residence time and variance of elution profiles may change with axial positions depending on the slip. © 2010 The Author(s).published_or_final_versionSpringer Open Choice, 31 May 201