(Dimethyl sulfoxide-κO)[2-({(ethyl­sulfan­yl)[2-(2-oxidobenzyl­idene-κO)hydrazin­yl­idene-κN 2]meth­yl}­imino­meth­yl)­phenol­ato-κO]dioxidouranium(VI)

Abstract

The UVI atom in the title complex, [U(C17H15N3O2S)O2(C2H6OS)], exists within a distorted penta­gonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the penta­gonal plane is defined by the N2O2 atoms of the tetra­dentate Schiff base ligand and the O atom of the dimethyl sulfoxide mol­ecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H⋯O inter­actions. The azomethine C=N atoms and ethyl­thiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio