Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Covalent attachment of a microporous polymer network (MPN) on a gold surface is presented. A functional bromophenyl-based self-assembled monolayer (SAM) formed on the gold surface acts as co-monomer in the polymerisation of the MPN yielding homogeneous and robust coatings. Covalent binding of the films to the electrode is confirmed by SEIRAS measurements.EC/FP7/278593/EU/Organic Zeolites/ORGZEODFG, EXC 314, Unifying Concepts in CatalysisBMBF, 03X5524, DELKAT - Hydrophobe Nanoreaktor Templatierung - Eine Tool-Box für optimierte Elektrokatalysatore