A model for the chemistry in a plasma fuel reformer or plasmatron has been developed. The plasma fuel reformer is set up to produce syngas (hydrogen and carbon monoxide gas mixture) from partial oxidation of hydrocarbons. The behavior of methane as fuel has been investigated to characterize and simulate the plasmatron performance. The goal of this work has been improved understanding of the physical/chemical processes within the reactor. The simulation tool used was CHEMKIN 3.7, using the GRI methane combustion mechanism. The Partially Stirred Reactor application (PASR) simulates random mixing by a frequency mixing parameter, which is directly dependant of the system fluid dynamic properties. The fuel reformer was designed as a reactor where combustion is initiated by an electric discharge due to ohmic heating of the arc region. From discharge observations, energy estimations and model simulations, it was found that the electric arc initiates combustion by locally raising the temperature and then propagating the reaction by heat and mass transfer/mixing to the surroundings. Simulation results demonstrated that there is an optimum characteristic mixing time for each residence time, depending on the initial temperature reached at the arc. It was also found that for given power input into the system, the more spread the energy is, or the more mass is heated to a moderate temperature, the better the calculated performance
