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Comparison of the effects of platinum and CeO2_2 on the properties of single grain, Sm-Ba-Cu-O bulk superconductors

Abstract

SmBa2_2Cu3_3O7δ_{7−δ} (Sm-123) is a light-rare-earth barium-cuprate (LRE-BCO) high-temperature superconductor (HTS) with significant potential for high field industrial applications. We report the fabrication of large, single grain bulk [Sm–Ba–Cu–O (SmBCO)] superconductors containing 1 wt% CeO2_2 and 0.1 wt% Pt using a top-seeded melt growth process. The performance of the SmBCO bulk superconductors containing the different dopants was evaluated based on an analysis of their superconducting properties, including critical transition temperature, TcT_c and critical current density, JcJ_c , and on sample microstructure. We find that both CeO2_2 and Pt dopants refine the size of Sm2_2BaCuO5_5 (Sm-211) particles trapped in the Sm-123 superconducting phase matrix, which act as effective flux pinning centres, although the addition of CeO2_2 results in broadly improved superconducting performance of the fully processed bulk single grain. However, 1 wt% CeO2_2 is significantly cheaper than 0.1 wt% Pt, which has clear economic benefits for use in medium to large scale production processes for these technologically important materials. Finally, the use of CeO2_2 results generally in the formation of finer Sm-211 particles and to the generation of fewer macro-cracks and Sm-211 free regions in the sample microstructure.This work was supported by the Engineering and Physical Sciences Research Council (Grant ID: EP/K02910X/1). Authors would like to acknowledge the support from project: APVV No. 0330-12, VEGA 2/0121/16

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