Among illegal human activities, marine pollution and target detection are the key concern of Maritime Security and Safety. This thesis deals with oil spill and ship detection using high resolution X-band polarimetric SAR (PolSAR). Polarimetry aims at analysing the polarization state of a wave field, in order to obtain physical information from the observed object. In this dissertation PolSAR techniques are suggested as improvement of the current State-of-the-Art of SAR marine pollution and target detection, by examining in depth Near Real Time suitability