The centrosymmetric title compound, [Pd2Cl2(C27H26N)2], was obtained by a C—H bond-activation reaction of a Schiff base ligand with Li2PdCl4 in methanol, and was crystallized from dichloromethane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement