THE VIBRATIONAL SPECTRUM OF DIMETHYLSULFIDE-BORANE

Abstract

Author Institution: Department of Chemistry, Geneva CollegeThe vibrational infrared spectrum of dimethylsulfide-borane in the liquid $(25^{\circ} C)$ and solid ($-196^{\circ} C$) states was studied from 4000 to $400 cm^{-1}$ as well as the Raman spectrum of the liquid sample. In addition the vibrational spectra of $(CH_{3})_{2}SB^{10}H_{3}$ and $(CH_{3})_{2}SBD_{3}$ were studied. The observed frequencies of the various samples and their assignments will be discussed on the basis of a $C_{***}$ molecular model for dimethylsulfide-borane