SPECTROSCOPIC EVIDENCE OF A PHASE CHANGE IN SOLID NORMAL HYDROGEN NEAR 1.4∘K1.4^{\circ}K.

Abstract

Author Institution: Department of Physics, The University of TorontoThe infrared fundamental band of solid normal hydrogen has been investigated over the temperature range 1.3 to 1.7∘K1.7^{\circ}K. Two features in the spectrum, the S1(0)S_{1}(0) line and the S1(1)S_{1}(1) line, vanish at a temperature of about 1.4∘K1.4^{\circ}K when the crystal is cooled. The features reappear at about 1.6∘K1.6^{\circ}K when the crystal is warmed. The temperature at which the transition takes place upon warming is close to the λ\lambda-a***omaly in the specific heat. The vanishing of the two spectral features can be explained if one assumes a phase transition to a crystal structure possessing inversion symmetry

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