Author Institution: Divisions of Pure Physics and Chemistry, National Research CouncilThe heat capacity of vitreous silica in the region T<20βK is very much larger than that observed for simple crystals. In order to interpret this unusual behaviour some spectroscopic studies have been made. The Brillouin spectrum excited by Ξ»2536.5 of Hg198 was photographed in the third order of a 35-ft. grating. Lines due to scattering by longitudinal waves were observed, together with much weaker lines attributed to transverse waves. Their frequency shifts form the exciting line are 1.68 and 1.04cmβ1 respectively. The shifts give directly the frequencies of the Debye waves producing the scattering namely, 5.03Γ1010Secβ1 and 3.12Γ1010Secβ1. Their velocities are in excellent agreement with the values determined by acoustic methods at a frequency of 107secβ1. These results show that dispersion of lattice waves in vitreous silica is not significant up to frequencies of about 5Γ1010secβ1. The Raman spectrum excited by Hg 2537 was photographed at low dispersion and in the fourth order of a 21-ft. grating. Its most prominent feature is an intense continuum starting below 8cmβ1 and extending to about 560cmβ1 where it has a sharp cut-off. These results give direct evidence for low frequency optical modes whose presence can account for the observed heat capacity. The origin of the spectrum is still a matter for speculation