The vapor pressure of four liquid 1H,1H-perfluoroalcohols (CF3(CF2)n(CH2)OH, n ¼ 1, 2, 3, 4), often called
odd-fluorotelomer alcohols, was measured as a function of temperature between 278 K and 328 K. Liquid
densities were also measured for a temperature range between 278 K and 353 K. Molar enthalpies of
vaporization were calculated from the experimental data. The results are compared with data from the
literature for other perfluoroalcohols as well as with the equivalent hydrogenated alcohols. The results
were modeled and interpreted using molecular dynamics simulations and the GC-SAFT-VR equation of
state