I. Murakami

J.G. Wang

T. Kato

National Institute for Fusion Science (NIFS-Repository)

§30. Dielectronic Recombination Processes in Li Isoelectronic Sequence Wang, J.G. *, Kato, T., Murakami, 1. Dielectronic Recombination (DR) can be re-garded as a resonant radiative recombination pro-cess. Its importance to influence the ionic balance in high temperature plasmas, such as solar corona, has been known for many years. Many theoreti-cal methods have been developed to cal culate the DR process, but it is still a tedious work to ob-tain the accurate DR rate coefficients since they invol ve many resonant doubly excited high Ryd-berg states. In the frame of quantum defect the-ory (QDT), we have developed a Simplified Rela-tivistic Configuration Interaction (SRCI) method to study the dielectronic recombination processes. In this method, the infinite resonant doubly ex-cited states involving high Rydberg state can be treated conveniently in a unified mannar by in-terpolation[l]. In this paper, we studied the DR processes for the Li isoelectronic sequence. DR from a state in the ground configuration of a Li like ion to a state in a Be like ion can be accomplished through L-shell or K-shell excitation can be represented by ls22s --t ls2nalanblb --t ls22l' n"l" + hv, (1) ls22s --t ls2lna lan blb --t ls2n'l'n"l" + hv.(2) There are two distinct classes in the L-shell excitation [Eq. (1)] that have quite different con-vergence characteristics along the doubly excited Rydberg series. The first ls22pnl, with no change in principal quantum number in the excited elec-tron (.6.n = 0), can only occur when the princi-pal quantum number n of the Rydberg electron is greater than a critical value no due to the energy conservation. With the increasing nuclear num-ber, the relativistic effects increase and the core energy splitting between ls22Pl/2 and ls22P3/2 be-come large, which will induce a very large no for ls22Pl/2 ( for example, no = 25 in Au75+ ion ). It is very diffcul t to calculate the wave function of the states with the high n, and the high Rydberg states will also involve many radiative transition processes. Using the SRCI method, we can treat all the Auger and radiative processes in a unified mannar, that is, we only calculate the Auger and Radiative rates for the states with n S 15, l S 13 and one according continuum state in a channel, and then we can obtain all the rates in the channel by interpolation in the frame of QDT. For the high Z ions, no > 15, the energy of continuum electron in Auger matrix elements can be calculated by the states n = no instead of the state n = 15. In this paper, we also check the validity of this interpola-tion. The second ls23lnl, involving change in the principal quantum number ( .6.n = 1 ), we take into account the contributions from all the states with l S 10, because the contributions from the states with higher l are not important. For K-shell excitation [Eq. (2)], explicit calculations were car-ried out for the ls2l2l' nl" with n S 5, l" S 4. All relativistic single-electron wavefunctions ( bound and continuum ) are calculated based on the atomic self-consistent potential. The config-uration wavefunctions are obtained by diagonal-izing the relevant Hamiltonian matrices. When the energy-normalized matrix elements of a few states ( including one continuum state) in a chan-nel have been calculated, the matrix elements of infini te discrete states of that channel can be cal-culated by interpolation, and all the Auger and radiative rates in the channel can be obtained. Then, we can calculate the DR cross sections or rate coefficients. In past decade, many detailed experiments have been performed to measure the DR cross sections or rate coefficients. In this pa-per, we calculate the DR processes for 5 ions with z = 6, 10, 18,28, 79, and all the results are com-pared with the experimental measurements. In order to use the rate coefficients conveniently, we also provide the partial DR rate coefficients to the excited states, and then fit them into a formula with two fitting parameters [2]. * Present address: Department of physics and As-tronomy, University of Georgia, Athens, GA 30602, USA. [1]. J.G. Wang, T. Kato, and I. Murakami, Phys. Rev. A60, 2104 (1999). [2]. J.G. Wang, T. Kato, and I. Murakami, Phys. Rev. A60, 3750 (1999). 383 

Dielectronic Recombination Processes in Li Isoelectronic Sequence

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