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Quality Indices of Fluoride Concentration in Groundwater of Malkhaid Sub-basin, Gulbarga District, Karnataka

Abstract

: Groundwater is the major source of drinking water in the study area., High fluoride content above permissible limit (>1.5 mg/l) are recorded at many places in groundwater samples of study area resulting in health hazards, causing dental and skeletal fluorosis. The major litho-units of study area are limestone, shales and Deccan traps. Integrated quality indices, multi-criteria decision making and sensitivity function analyses are used to analyze the groundwater samples using mathematical modelling. The geochemistry of groundwater relating major ionic constituents with fluoride using statistical analysis are carried out to understand the source and mechanism of enrichment of fluoride in groundwater. Based on multi-criteria decision making approach, the majority of the samples fall under the category of decreased quality region. Results of sensitivity function analyses indicate, waters belong to less recommended range. Saturation indices of fluoride minerals are interpreted using Chadha’s diagram. The geochemical analysis indicates the alkalis, viz., Ca2+ and Mg2+ indicated negative correlation with fluoride. This could be due to the oversaturation of carbonate minerals as inferred from saturation indices. Positive correlation between Fwith that of Na+ ions and pH is observed, which may be due to the rock dissolution processes. From the above studies it is interpreted that the mineral dissolution through rock water interaction is the major controlling process of fluoride enrichment in groundwater. Water treatment and de-fluorination at village levels are to be considered for using groundwater for drinking purpose

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