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Suppression of the alpha -> beta-nickel hydroxide transformation in concentrated alkali: Role of dissolved cations

Abstract

The presence of dissolved cations such as Al and Zn in alkaline electrolyte (6 M KOH) suppresses the alpha --> beta-nickel hydroxide transformation. The uptake of Al (10 mol%) and Zn (30 mol%) exhibited by the active material likely stabilizes the alpha-phase. Dissolved Al is deleterious to the performance of the nickel hydroxide electrode, whereas, dissolved Zn enhances the specific discharge capacity of nickel hydroxide by approximately 25% showing that the mode of metal uptake is different in the two cases

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