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Layered double hydroxides of Ni with Cr and Mn as candidate electrode materials for alkaline secondary cells

Abstract

The use of layered double hydroxides (LDH) of Ni with Cr and Mn as electrode materials for alkaline secondary cells was studied. The presence of Cr and Mn suppresses β-nickel hydroxide formation which indicates their strong influence on the precipitation behavior of Ni2+. It is found that the LDH of Ni with Cr and Mn are electrochemically active and deliver capacities of 500 (Ni-Cr), 400 (Ni-Mn, x = 0.2) and 430 (Ni-Mn, x = 0.1) mAhg-1 of Ni respectively

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