Complexes of divalent cadmium with N,N-dimethyl-3-dibenzob,e-oxepin-11-(6H)-ylidine-1-propanamine)chloride: Synthesis and evaluation of thermal degradation kinetics

Abstract

A tricyclic antidepressant drug doxepin (C19H21NO), abbreviated as DOX, forms complex with divalent cadmium metal of the type Cd(DOX)2X2 (X = Cl-, Br-, NO 3 -, I-, 1/2SO4 2- or CH3COO-). In all the complexes, DOX coordinates through side-chain nitrogen atom. The TG data of degradation of the complex have been analyzed for kinetic and thermodynamic parameters employing Briodo's method

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