Synthesis of bis-oxathiaaza[3.3.3]propellanes via nucleophilic addition of (1,ω-alkanediyl)bis(N′-organylthioureas) on dicyanomethylene-1,3-indanedione
A concise and efficient route for synthesis of bis-oxathiaaza[3.3.3]propellanes by reaction of N,N,-N″-(1,ω-alkanediyl)bis-(N″-organylthioureas) with (1,3-dioxo-2,3-dihydro-1H-inden-2- ylidene)propanedinitrile is reported. The structures of the products have been confirmed by using NMR as well as single crystal X-ray analysis for one product. A plausible mechanism for formation of the products is presented.Peer reviewe
