Do the Defects Make it Work? Defect Engineering in π - Conjugated Polymer Films and Their Solar Cells

Abstract

The summaries of this report are: (1) charged defects produce 10{sup 15}-10{sup 17} cm{sup -3} free carriers; (2) treatment with nucleophiles decreases p{sub f} and {sigma} while treatment with electrophiles does not change p{sub f} but increases {sigma}; (3) both treatments increase {mu}{sub p}, L{sub ex} and stability against photo-degradation; (4) charged defects can improve OPV by increasing conductivity and creating interfacial electric fields but they hurt {mu}{sub p}, L{sub ex} and chemical stability; and (5) a better way--synthesize materials without covalent defects and dope with purposely added, bound dopants

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