Moll, Jeremie D.

Roesner, Faculty Advisor, Rebecca

Digital Commons @ Illinois Wesleyan University

Illinois Wesleyan UniversityDigital Commons @ IWUJohn Wesley Powell Student ResearchConference 2000, 11th Annual JWP ConferenceApr 15th, 2:00 PM - 3:00 PMSynthesis of Bis(Hexamolybdate) ComplexesCovalently Bridged by Organnoimido LigandsJeremie D. MollIllinois Wesleyan UniversityRebecca Roesner, Faculty AdvisorIllinois Wesleyan UniversityFollow this and additional works at: http://digitalcommons.iwu.edu/jwprcThis Event is brought to you for free and open access by The Ames Library, the Andrew W. Mellon Center for Curricular and FacultyDevelopment, the Office of the Provost and the Office of the President. It has been accepted for inclusion in Digital Commons @ IWU bythe faculty at Illinois Wesleyan University. For more information, please contact digitalcommons@iwu.edu.©Copyright is owned by the author of this document.Jeremie D. Moll and Rebecca Roesner, Faculty Advisor, "Synthesis of Bis(Hexamolybdate) Complexes Covalently Bridgedby Organnoimido Ligands" (April 15, 2000). John Wesley Powell Student Research Conference. Paper 15.http://digitalcommons.iwu.edu/jwprc/2000/posters2/15THE JOHN WESLEY POWELL STUDENT RESEARCH CONFERENCE ' APRIL 2000 Poster Presentation 34 SYNTHESIS OF BIS(HEXAMOLYBDATE) COMPLEXES COVALENTLY BRIDGED BY ORGANOIMlDO LIGANDS Ieremie D. Moll and Rebecca Roesner* Department of Chemistry, Illinois Wesleyan University Figure 1 Rotaxanes are supermolecular structures composed .of linear molecules threaded through macrocyclic molecular rings and held in place by the addition of large blocking groups to prevent dethreading (Figure 1). Polyoxometalates, such as hexamolybdate ions, are extremely large, highly symmetric clusters that can be used as the blocking groups for rotaxane preparation. Our intent has been to synthesize a Bis(Hexamolybdate) complex to serve as the dumbbell for our rotaxane through the use of difunctional amine linkers. Our current goal is to purify the synthesized complex (Figure 2) and then repeat the procedure with the macrocyclic molecule in place. Figure 2 

Synthesis of Bis(Hexamolybdate) Complexes Covalently Bridged by Organnoimido Ligands

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Synthesis of Bis(Hexamolybdate) Complexes Covalently Bridged by Organnoimido Ligands

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