Well-dispersed MnO2 micro-flowers were grown directly on carbon nanofibers via a simple hydrothermal technique without any template. Structure and morphology were characterized by X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM) equipped with rapid energy dispersive analysis X-ray (EDX). The appealed characterization techniques specified that the obtained material is carbon nanofibers decorated by MnO2 micro-flowers. Super capacitive performance of the MnO2 micro-flowers decorated CNFs as active electrode material was evaluated by cyclic voltammetry (CV) in alkaline medium and yield a reasonable specific capacitance of 120 Fg−1 at 5 mV s−1. As an electrocatalyst for hydrazine oxidation, the MnO2 micro-flowers decorated CNFs showed high current density. The impressive bi-functional electrochemical activity of MnO2 micro-flowers decorated CNFs is mainly attributed to its unique architectural structure.This Research was financially supported by National Research Foundation of Korea (NRF) Grant funded by the Korean Government (MSIP) (No. 2014R1A4A1008140