This article presents an initial empirical assessment of a new analytical framework of styles of volunteering (SOV). The framework suggests that volunteering can be categorized in terms of a multidimensional set of cultural and structural indicators that cohere in systematic and varying ways. With data drawn from a survey of 652 Flemish Red Cross volunteers, a multivariate analysis reveals five different SOV categories of volunteers: episodic contributors, established administrators, reliable coworkers, service-oriented core volunteers, and critical key figures. The research findings indicate that the volunteer reality is far more complex than suggested by conventional approaches to the study of volunteering