Marosi, György

Molnár, Kolos

Szebényi, Gábor

Szolnoki, Beáta

Toldy, Andrea

Tóth, Levente Ferenc

English

Ghent University Academic Bibliography

CENTRE OF PHARMACEUTICAL,      ENVIRONMENTAL- AND           SAFETY MATERIALSBudapest University of Technology and EconomicsDepartment of Organic Chemistry and TechnologyDepartment of Polymer EngineeringFLAME RETARDANCY OF EPOXY RESIN COMPOSITESREINFORCED WITH CNT-LOADEDCARBON NANOFIBRE Beáta Szolnoki, Levente Ferenc Tóth, Kolos Molnár, Gábor Szebényi, Andrea Toldy, György Marosibszolnoki@mail.bme.hu AcknowledgementThis work is connected to the scientific program of the "Development of quality-oriented and harmonized R+D+I strategy and functional model at BME" project supported by the New Széchenyi Plan (Project ID: TÁMOP-4.2.1/B-09/1/KMR-2010-0002).The research leading to these results has received funding from the European Union's Seventh Framework Programme (FP7/2007-2013) for the Clean Sky Joint Technology Initiative under grant agreement n° 270599.References[1] G Marsh, Reinforced Plastics 54 (2010) 20-24.[2] N Yamamoto, RG de Villoria, BL Wardle, Comp. Sci. Tech. 72 (2012) 2009-2015.[3] K Molnár, E Košt'áková, L Mészáros, Mater. Sci. Forum 589 (2008) 221-226.[4] JG Kovács, A Suplicz, J. Reinf. Plast. Comp (2013)DOI:10.1177/0731684413489755ConclusionsIn this work CNT-loaded carbon nanofibre-carbon fibre reinforced hybrid epoxy resin composites were prepared and tested. The CNT-loaded nanofibres were produced via elecrospinning, followed by stabilization and carbonization in order to prepare hybrid nano reinforcing carbon fibres. The epoxy resin matrix also contained CNT. The application of the nanomaterial increases the thermal conductivity of the composites, however the effect of the nanofibres is negligible. In the cone calorimeter, when no carbon fibre reinforcement is applied, the CNT decreases the pHRR of the samples. In the hybrid composites, due to the increased heat conductitvy, the samples burn easier, however no significant difference can be found. The LOI values increase with the incorporation of carbon fabrics, and also in UL-94 test only vertical burning can be observed.IntroductionThe use of the parts made of composites of high mechanical loading capability, being suitable for replacing metallic structures, is rapidly increasing in the aircraft industry [1]. In the newest large airliners the fuselage, the wings and the empennage are also made of carbon fibre reinforced composites. For enhancing the thermal and electrical conductivity of these composites, CNTs can be incorporated into the matrix [2], or into the reinforcing fibres. The electrospinning method provides a simple and cost-effective method to produce ultra fine fibres even with the deposition of carbon nanotubes (CNTs) inside the nanofibres [3]. Considering the flammability of the composites, the incorporation of the carbon fibres has a reducing effect. By the addition of CNT to epoxy resins, improved thermal stability can be reached.MaterialsAs matrix material, CL-12 glycerol-based epoxy resin was used, cured with T-111 anhydrid-type hardener (IPOX Chemicals, Hungary) .O OO OOOOOOAs conventional carbon fibre reinforcement, Zoltek PX35FBUD0300 type unidirectional fabric was used. The fabric consisted of Panex 35 50k rovings and had a surface weight of 333 g/m2.Baytubes C 150 HP (Bayer, Germany), multiwalled carbon nanotubes were used as nanosized reinforcement both in the matrix and in the nanofibers.  ElectrospinningA: Polymer solution feedB: Spinneret electrodeC: High voltage power supplyD: Space of fiber formationE: Collector electrodeThe electrospinning was carried out from a 12 wt% PAN solution in DMF solvent. The amount of the dispersed nanotubes was 2 wt% of the mass of the polymer precursor. CNTs were dispersed in the solution by ultrasonic mixing.The method uses electrostatic forces to draw the fibres from the polymer solution. The electrostatic field between the two electrodes is provided by a high voltage power supply. Because of the applied field strength, a cone-shape, called Taylor cone is formed from the polymer droplet and a thin jet emerges from the tip of this cone. This jet elongates and solidifies as it travels to the collector. In case of a basic set up, a nanofibrous mat structure is formed on the collector electrode.1: rotary electrode, 2: grounded plate electrode, 3: high voltage power supply, 4:  solution, 5: fiber formation space, 6: rollersStabilization, carbonizationIn order to prepare carbon nanofibres from the electrospun PAN mat, stabilization followed by carbonization must be carried out. During the stabilization, the cyclization of the polymer takes place. CHCCH2CHCCH2CHNNCNCCCHCCCHCNNCair280 °C17 minAftet that, the carbonization requires high temperature (up to 830 °C) to provide fully graphitized structure for the electrospun nanofibrous mat.LOI and UL-94When no conventional carbon fabric reinforcement (cC) is used, the samples can be ignited easily. When CNTs are present in the matrix, the flame spreading rate is 70% higher. When cC is used, the LOI value increases by about 7 V/V%, and no flame spreading can be detected in the UL-94 test. Considering the LOI values,no significant difference can be  detected in the case of the cC r e i n f o r c e d samples, in spite of the CNT or nF content.Thermal conductivityAs the flammability of the materials depends also on the heat conductive properties, the thermal conductivity [4] was also determined for several samples (EcC, EcCT, EcCnF_I  0.6070.7640.5650.6700.10.20.30.40.50.60.70.80.9EcC EcCT EcCnF_I EcCTnF_IThermal conductivity (W/mK)and EcCTnF_I). The CNT loading in the matrix increases the thermal conductivity of the samples,      however, the presence of the CNT-loaded nano-fibres (nF) has no significant effect, moreover, the values  measured for these samples are some-what lower.Cone calorimeter tests01002003004005006007008000 100 200 300 400 500 600HRR (kW/m2 )time (sec)EcCEET0501001502002500 100 200 300 400 500HRR (kW/m2 )time (sec)EcCTEcCTnF_IEcCTnF_TBEcCTnF_All01002003004005000 100 200 300 400 500HRR (kW/m2 )time (sec)EnF_TBETnF_TBEcCnF_TBEcTnF_TBThe CTN-loading in the matrix lowers somewhat the pHRR in neat resins, but when applied together with carbon fibres, the effect is inverse. The CNT-containing nanofibres have no significant effect in the cone calorimeter tests.Sample preparationFor the flame retardancy measurements 12 samples were prepared by vacuum-bag method. The fabrics were impregnated with the resin and then cured at80 °C for 8 hours. The CNTs were dispersed in the matrix using masterbatch mixing technology.

Flame retardancy of epoxy resin composites reinforced with CNT-loaded carbon nanofibre

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Flame retardancy of epoxy resin composites reinforced with CNT-loaded carbon nanofibre

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