Capelli, Laura

Eusebio, Lidia

Sironi, Selena

EUSEBIO, LIDIA GIUSEPPINA

SIRONI, SELENA

CAPELLI, LAURA MARIA TERESA

Archivio istituzionale della ricerca - Politecnico di Milano

  ELECTRONIC NOSE FOR CONTINUOUS EMISSION MONITORING AND ODOUR CONCENTRATION MEASUREMENT: CASE STUDY AT A WASTE WATER TREATMENT PLANT  Lidia Eusebio, Selena Sironi*, Laura Capelli Politecnico di Milano, Department of Chemistry, Materials and Chemical Engineering “Giulio Natta” lidiagiuseppina.eusebio@polimi.it, selena.sironi@polimi.it, laura.capelli@polimi.itABSTRACT One extremely interesting and useful application of electronic noses is the continuous monitoring and control of environmental odour emissions. The possibility of continuously characterizing an odour emission over time by means of an electronic nose allows to account for the fluctuations that are typical of some emission typologies, thus providing a better description of the effective odour impact. This study discusses the possibility of installing an electronic nose directly at an emission, with the purpose of continuously measuring the odour concentration and thus to obtain data that could be possibly used as real-time inputs for dispersion models. As target emission we chose a stack that conveys the exhaust gases from the wastewater pretreatment and the sludge treatment unit at a waste water treatment plant. An EOS 507 electronic nose appositely developed with SACMI Imola S.C. was first trained in laboratory both with pure compounds in order to verify the instrument capability to correctly estimate odour concentrations. The results obtained suggest that the odour concentration values measured by the electronic nose are consistent and reliable. Index terms– electronic nose, odour emissions, odour concentration, continuous monitoring 1. INTRODUCTION The presence of odour in ambient air is nowadays recognized as an environmental stressor that negatively affects the quality of life. In order to evaluate odour exposure at receptors, several methods can be applied [1]. Different regulations provide to use dispersion modelling to simulate how odour disperses into the atmosphere, and consequently to calculate hourly ground odour concentration values in the simulation space-time domain [2-4]. Given that a detailed characterization of emissions over time would require frequently repeated olfactometric analyses, thus resulting in a very expensive (in terms of money and time) approach, emission data employed as model inputs are usually single or averaged values derived from one or few olfactometric analyses. This approach may provide a good description of the average odour impact, but doesn’t take account of fluctuations that are typical of some emission typologies [5]. This study discusses the possibility of installing an electronic nose directly at an emission, in order to measure odour concentration continuously and therefore to obtain real-time data to be used as inputs for dispersion models.  The studied emission is the exhaust line from the wastewater pretreatment and the sludge treatment unit at a civil wastewater treatment plant. In this work the first results of this project are presented. First, chemical analyses were conducted with the aim of identifying the chemical substances contained in the exhaust gas in order to optimize the sensor array. Then, laboratory tests were conducted to evaluate the electronic nose capability of quantifying odour concentration. The tests were conducted using “artificial” samples prepared with compounds (pure and mixed) that were identified in the target emission. 2. MATERIALS AND METHODS 2.1 The EOS 507 electronic nose  The electronic nose used for this work is an EOS 507 produced by SACMI Imola S.C.. The instrument has two inlets: one is connected with the system for the neutral air realization; while the other is connected with an electronic valve that regulates the sample flow to the sensor chamber, which contains 6 MOS sensors, specifically selected for this application. The electronic nose is equipped also with a temperature and humidity sensor. 2.2 Instrument training The emission considered for this study is a stack conveying the exhaust gases from the wastewater pretreatment and the sludge treatment unit at a waste water treatment plant. The exhausts are treated by a scrubber before emission. Specific chemical analyses were conducted in order to determine the composition of the emission. The main odorous compounds identified in the target emission were used in order to prepare “artificial” samples, i.e. pure compounds and mixtures of those compounds at different concentrations for the electronic nose training. 2.3 Tests with target odours  The compounds to be used for the laboratory tests were chosen among those identified in the target emission by means of chemical analyses. More in detail, the Odour Activity Value (OAV) [2] relevant to each compound was evaluated as the ratio between the measured chemical concentration and the odour threshold concentration (Table 1). The compound having the highest OAV turned out to be H2S, which was thus selected as target compound for laboratory tests. Also other compounds associated with urine odour were identified, such as ammines, sulphur compounds and ketones. For this reason, besides H2S, we decided to use urine odour obtained from an artificial l urine fluid, appositely developed by our research group within another research project in order the same odour concentration and hedonic tone with respect to real urine [6]. Gaseous samples of each target odour were analysed by means of the electronic nose at different concentrations in order to create a suitable training dataset for the estimation of odour concentration (Table 2). After the training, other gaseous samples were analysed as test set, whereby the instrument   estimated their odour concentration. The odour concentration of analysed samples was in the range between 16 and 6500 ouE/m3. For the odour quantification, two different approaches were considered:  • “Single” training dataset: for each target odour, only the corresponding training dataset was considered (e.g. H2S testing using H2S training dataset only); • “Complete” training dataset: both training datasets were considered together as a unique training dataset (e.g. H2S testing used training datasets relevant both to H2S and urine). 3. RESULTS 3.1 Tests with target odours  Some results of the tests for the estimation of the odour concentration by electronic nose with the target odours are shown in Table 3, which reports both the “real” (by “real” the odour concentration determined by dynamic olfactometry is meant) and the estimated odour concentration values; as well as the per cent error relevant to the estimations. The per cent error relevant to the odour concentrations estimated by the electronic nose is comprised between 1.4 and 85 %, depending on the type of training dataset used and the odours analysed. More in detail, the highest errors (72% and 85%) are observed for the H2S sample at the lowest concentration (1600 ouE/m3). This may be connected to the extremely low odour threshold concentration of H2S (Table 1), which makes that an odour concentration of 1600 ouE/m3 corresponds to an analytical concentration of about 0.5 ppm. As a matter of fact, accurate recognition at such low concentration levels appears problematic. This is also evident from the per cent errors relevant to the artificial urine sample, which are much lower (<6%). Another interesting observation is that some improvement of the estimation accuracy is obtained using the “single” training instead of the “complete” training set. This observation requires further experimental observations in order to be confirmed. 4. CONCLUSIONS The results of the preliminary laboratory tests discussed in this abstract show that the EOS 507 is able to quantify the odour concentration of samples of pure compounds with an accuracy that is comparable with the uncertainty of dynamic olfactometry. The per cent error observed towards the tested target odours is comprised between 1.4 and 85%. The capability of the system to estimate the odour concentration is dependent from the training dataset used. 5. FUTURE WORK The first implementation of this work consists in the training of the electronic nose with real samples collected at the plant and then in the installation in the field, i.e. at the stack at the wastewater treatment plant, in order to measure the odour concentration continuously. Further laboratory tests will also be required in order to investigate the dependence of the estimation accuracy from the training procedures as well as from the type of odour. 6. REFERENCES [1]  L. Capelli, S. Sironi, R. Del Rosso, J.-M. Guillot, “Measuring odours in the environment vs. dispersion modelling: A review”, Atmospheric Environment, vol. 79, pp. 731-743, 2013. [2] G. Cusano, C. Licotti, S. Sironi, L. Capelli, A.N. Rossi, M. Il Grande, “Odour regulation in Italy: the regional guidelines on odour emissions in Lombardia”, Chemical Engineering Transactions, vol. 23, pp. 19-24, 2010. [3] Integrated Pollution Prevention and Control (IPPC), 2002. IPPC Guidance H4: HorizontalGuidance for Odour, Part 1—Regulation and Permitting. Environment Agency UK, Bristol, UK. [4] JORF, 2008 Journal Officiel de la République Française (JORF) Arrêté du 22 avril 2008 fixant les règles techniques auxquelles doivent satisfaire les installations de compostage ou de stabilisation biologique aérobie soumises à autorisation en application du titre Ier du livre V du code de l'environnement JORF n°0114 du 17 mai 2008  (2008) [5] I. Isaac-Ho Tin Noe, F. Siino, C. Bara, Y. Urvoy, C. Haaser, A. Tripathi, L. Ait Hamou, T. Mailliard, “Tool for predicting and monitoring the impact of wastewater treatment plants on odour”, Chemical Engineering Transactions, vol. 23, pp. 267-272, 2010. [6] S. Sironi, L. Capelli, L. Dentoni, R. Del Rosso “Methodology for assessing the performance of urine absorbing aids in controlling malodour release”, International Journal of Cosmetic Science, vol. 35, pp. 321–328, 2013.  Table 1. Concentration of compounds identified by chemical analysis, their odour threshold concentrations (OT) and the estimated OAV  Compound Concentration [ppm] Odour Threshold [ppm/ouE] OAV [ouE/m3] H2S 0.43 3.21E-04 1340 Ammonia 1.00 4.65 0.22 Table 2. Odour concentrations of the target odour samples used for instrument training and testing Sample Odour Concentration  Training set [ouE/m3] Test set [ouE/m3] H2S 65-6500 1600, 3250, 6500 30-3200 16-1600 Artificial Urine 12-1250 1250 6-630 Table 3. Real and estimated odour concentrations relevant to the tests with the target odours conducted using “single” and “complete” training dataset Sample Odour Concentration Type of training dataset Real [ouE/m3]Estimated [ouE/m3] Error% H2S 1600 447 72% Single training dataset H2S 3250 3294 1.4% H2S 6500 4997 23% Artificial Urine 1250 1320 6% H2S 1600 2958 85% Complete training dataset H2S 3250 4265 31% H2S 6500 2891 56% Artificial Urine 1250 1220 2%    

Electronic Nose for continuous emission monitoring and odour concentration measurement: case study at a waste water treatment plant

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Electronic Nose for continuous emission monitoring and odour concentration measurement: case study at a waste water treatment plant

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