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Thermal Stability and Antibacterial Activity of a Newly Prepared Organic Coating from a De-saturated Seed Oil of Thevetia Peruviana

Abstract

Air drying polyesteramide-urethanes resins were synthesized from de-saturated fatty methyl ester (FAME) of Thevetia peruviana seed oil commonly known as Yellow oleanda (a tropical ornamental shrub) having about 68.8% unsaturated and 30.9% saturated fatty acids. Urea fractionation method was used to optimize the percentage of functional groups (in this case double bonds) by physio-sorption of the saturated fatty acids. The physico-chemical characterization of the optimized unsaturated FAME such as hydroxyl value, iodine value, saponification value, refractive index, inherent viscosity were carried out using standard methods. Through condensation reaction the N,N- bis(2-hydroxyethyl) Thevetia peruviana (HETA) prepared from the FAME react with isophthalic acid to form polyesteramide. The latter undergo urethanation with H1 • 2 MDI. The structural elucidation of the moisture cured polyesteramide-urethane urethane coating was based on FTIR, 1H-NMR and 13C-NMR spectroscopic methods. The coatings films were evaluated for its antibacterial activity and thermal stability properties on TGA and DSC. SEM of the coating films was also examine

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