Reactions of methylene active compounds with peroxo-rhodium phosphino complexes. Formation of hydro-peroxorodhium complexes.

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Publication date
1 January 1987
Publisher
Elsevier BV:PO Box 211, 1000 AE Amsterdam Netherlands:011 31 20 4853757, 011 31 20 4853642, 011 31 20 4853641, EMAIL: [email protected], INTERNET: http://www.elsevier.nl, Fax: 011 31 20 4853598

Abstract

Reactions of active methylene compounds HA (malononitrile, \u3b2-diketones, cyclopentadiene) with the dioxygen adduct [Rh(dppe)O2]BF4 give new hydroperoxorhodium(III) complexes of the type [Rh(dppe)(A)OOH]BF4. The complexes readily convert PPh3 into OPPh3, but do not oxidise ketones or olefins, which instead undergo extensive isomerization

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