research

Synthesis, Characterization and Structure of Dioxomolybdenum(VI) Complexes of Aroylhydrazones

Abstract

The reactions between Schiff base ligands derived from carbonyl compound and acid hydrazides and [MoO2(acac)2] in the presence of solvent (Alcohol) yielded three dioxomolybdenum(VI) complexes with the general formula [MoO2L1-3(Alcohol)] (1-3), where L = tridentate Schiff base ligand. One (complex 1) of the three complexes reported here has been fully characterized by elemental analysis, IR, UV-visible and NMR spectroscopy. This study indicates that the hydrazone ligand (e.g., H2L1) has the normal tendency to form monomeric complex coordinated in the form of dianionic tridentate manner

    Similar works