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Spectroscopic evidence for large (>>1 µm) lithium-colloid creation in electron-irradiated Li2O single crystals

Abstract

We have created lithium metal colloids by electron-irradiating single crystals of lithium oxide near 0°C. The striking feature is the observation of two kinds of colloids manifesting themselves as two EPR metallic lines, the narrow line corresponding to small metallic clusters (size < 1 µm) and the broad one associated with large metallic colloids visible by optical microscopy (~ 20 µm). The latter are also observed by NMR. A further indication for the presence of colloids of different types is the differing recovery behavior of the two EPR lines in an annealing treatment

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