We demonstrate in this paper a super-hydrophilic and oleophobic green porous photothermal material based on wood fiber as a novel oil-repellent photothermal material for efficient solar vapor generation (WF-SP). WF-SP is an excellent light-absorbing material with the advantages of a porous nanostructure, super-hydrophilic, low thermal conductivity, high-temperature resistance, and oleophobicity. Based on these advantages, WF-SP exhibits good solar photothermal conversion performance with solar vapor generation efficiencies of 85.4%, 75.3%, and 70.2% at 1 kW m−2, 2 kW m−2, and 3 kW m−2 radiation intensities, respectively. The results provide new possibilities for the design and preparation of low-cost, green, and pollution-free photothermal materials with high solar thermal conversion efficiency for solar photothermal conversion vapor generation.</p