Department of Chemistry, Tokyo Metropolitan University
Abstract
Two Antarctic achondrites, Yamato (Y)-74359 and Y-74360,are very similar in bulk chemical compositions to the silicate portions of H chondrites, but the siderophile elements are extremely depleted in comparison to those of H chondrites. They consist of olivine, pyroxene and cryptocrystalline feldspar with minor amounts of chromite, kamacite, and troilite, and the chemical compositions of the constituent minerals are similar to those in H chondrites. Taking into consideration that the two achondrites have oxygen isotopic compositions typical of H chondrites, they were produced from H chondrites or the precursors of H chondrites. Chondrules are not observed, and the texture of the two achondrites is similar to one another, although Y-74360 is coarser-grained than Y-74359. Olivine occurs as euhedral or subhedral grains, mostly smaller than 100 microns in diameter, and they show slight chemical zoning, from magnesian cores (Fo_) to ferroan rims (Fo_). Orthopyroxene occurs as euhedral grains, larger than olivine grains, and also shows slight chemical zoning, from Ca-poorer magnesian cores to Ca-richer ferroan rims. Clinopyroxene occurs as rims of orthopyroxenes and shows remarkable chemical zoning continuously from pigeonitic interiors to augitic rims. Cryptocrystalline feldspar occurs in interstitial spaces between olivine and/or pyroxene, and seems to have crystallized in interstitial liquids in a rapid cooling condition. The cryptocrystalline feldspars in Y-74359 are chemically heterogeneous, classified into three groups, albite (An_Ab_Or_), anorthoclase (An_Ab_Or_), and intermediate alkali feldspar (An_Ab_Or_), and occur in different portions of the thin section. The two achondrites seem to have formed by partial melting from heterogeneous silicate precursors of unequilibrated H chondrites
