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一种铜(Ⅱ)配位聚合物的水热合成和表征
Authors
姚建曦
徐文国
王丹
聂超
Publication date
1 January 2006
Publisher
Abstract
在水热条件下,使用2,2'-联吡啶作为配体合成了一种二价铜配位聚合物单晶,并通过X射线粉末衍射、单晶X射线衍射、红外光谱、紫外可见光谱、热分析等手段对该化合物进行了表征。结果表明,该化合物晶胞参数为a=1.5118(3)nm,b=1.2439(7)nm, c=0.7000(6)nm,β=106.02(4)°,V=1.2654(3)nm3,且与用同样方法合成出来的[Cu(1,10-phenanthroline)(H2O)2SO4]n具有相似的结构
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Last time updated on 09/11/2016