Laser-Induced Breakdown Spectroscopy of silicon was performed using a nanosecond pulsed frequency
doubled Nd:YAG (532 nm) laser. The temporal evolution of the laser ablation plumes in air at atmospheric
pressure and at an ambient pressure of ∼10−5 mbar is presented. Electron densities were determined from
the Stark broadening of the Si (I) 288.16 nm emission line. Electron densities in the range of 6.91×1017 to
1.29×1019 cm−3 at atmospheric pressure and 1.68×1017 to 3.02×1019 cm−3 under vacuum were observed.
Electron excitation temperatures were obtained from the line to continuum ratios and yielded temperatures
in the range 7600–18,200 K at atmospheric pressure, and 8020–18,200 K under vacuum. The plasma
morphology is also characterized with respect to time in both pressure regimes