Charge Transport in Single Molecule Junctions of Spirobifluorene Scaffold

Abstract

Single molecule conductance of two spirobifluorene molecules of different length have been studied by scanning tunneling break junction (STM–BJ) methodology. First molecule contains a tripodal spirobifluorene platform, whereas a second one contains the same platform with chemically attached p-phenyleneethynylene molecular wire. The conductance values change only slightly between these two molecules, which demonstrated that such a platform provides both highly conducting pathway and stable anchor for the future molecular electronic devices