Preliminary results from a new measurement of the Ke4 decay K±→π+π−e±ν by the Na48/2 collaboration at the CERN SPS are reported. An unprecedented sample of more than 670000 Ke4 decays in both charged modes have been collected in 2003. The form factors of the hadronic current (F, G, H) and phase shift (δ00−δ11) of the ππ scattering have been measured using a model independent method and their variation with the ππ mass has been investigated. First evidence for a non zero fp term is reported. Thanks to a sizeable acceptance at large ππ mass, a low background and a very good resolution, an improved accuracy (±0.006stat±0.005syst) can be reached when extracting the ππ scattering length a00 . Using more elaborated theory inputs and another NA48/2 result from K±→π0π0π± decays, a consistent picture can be drawn for the scattering lengths a00 and a02 , in good agreement with Chiral Perturbation Theory predictions