Solid-state combustion synthesis of ceramics and alloys in reduced gravity

Abstract

Possible microgravity effects are explored in the combustion synthesis of ceramics and alloys from their constituent elements. Molten intermediates are typically present during the combustion process, thereby offering the chance for natural convection to take place. Numerical simulations suggest that the combustion front in concert with gravity may act as a partial zone-refinement mechanism which is attempting to sweep out porosity in the sample. Contrary to suggestions by dimensional analysis, no effects on the combustion rate are seen. An analytical model of the combustion velocity as a function of the gravitational field and the spreading rate of molten material gives the correct order of magnitude of the gravity effect as measured by centrifuge experiments