Ignition and combustion of metals in oxygen

Abstract

Tests in which metals were rubbed against themselves in oxygen have revealed that increasing oxygen pressure does not always increase the potential for ignition. It is believed that there exists a specific pressure above which convective heat loss due to higher oxygen density will overcome the potential increase in the oxidation rate afforded by the increase in oxygen pressure. Test results have shown that, once a specific oxygen pressure is exceeded, greater rates of frictional energy were required for ignition of metals as pressure is increased. Other test results have indicated that as oxygen pressure is increased during the rubbing process, the bulk sample equilibrium temperatures decrease. These results support the belief that increases in convective heat loss as pressure is increased can raise the energy requirements for ignition of metals or lower their ignition potentials. Testing has also indicated that, when metals were exposed to a rubbing process and oxygen pressure was increased, metals such as carbon steel exhibited a decrease in their bulk ignition temperatures, whereas metals such as Monel showed bulk ignition temperatures independent of pressure