Evaluation of the Strecker synthesis as a source of amino acids on carbonaceous chondrites

Abstract

The Strecker synthesis (SS) has been proposed as the source of amino acids (AA) formed during aqueous alteration of carbonaceous chondrites. It is postulated that the aldehyde and ketone precursors of the meteoritic AA originated in interstellar syntheses and accreted on the meteorite parent body along with other reactant species in cometesimal ices. The SS has been run with formaldehyde, acetyldehyde, propionaldehyde, acetone, and methyl ketone as starting materials. To study the effect of minerals on the reaction, the SS was run in the presence and absence of dust from the Allende meteorite using deuterated aldehydes and ketones as starting materials. The products were studied by GC/MS. With the exception of glycine, the retention of deuterium in the AA was greater than 90 pct. Some D exchange with water does occur, however, and determination of the rate of exchange as a function of pH and temperature may allow some bounds to be placed on the duration of parent body aqueous alteration. The retention of D by the AA under conditions studied thus far is consistent with the model that a SS starting from interstellar aldehydes and ketones led to the production of meteoritic AA