Transient four-wave mixing studies of bulk GaAs under conditions of broad
bandwidth excitation of primarily interband transitions have enabled
four-particle correlations tied to degenerate (exciton-exciton) and
nondegenerate (exciton-carrier) interactions to be studied. Real
two-dimensional Fourier-transform spectroscopy (2DFTS) spectra reveal a complex
response at the heavy-hole exciton emission energy that varies with the
absorption energy, ranging from dispersive on the diagonal, through absorptive
for low-energy interband transitions to dispersive with the opposite sign for
interband transitions high above band gap. Simulations using a multilevel model
augmented by many-body effects provide excellent agreement with the 2DFTS
experiments and indicate that excitation-induced dephasing (EID) and
excitation-induced shift (EIS) affect degenerate and nondegenerate interactions
equivalently, with stronger exciton-carrier coupling relative to
exciton-exciton coupling by approximately an order of magnitude. These
simulations also indicate that EID effects are three times stronger than EIS in
contributing to the coherent response of the semiconductor
