Gas-Liquid Chromatographic Method for the Analysis of Microencapsulated Diazinon Insecticide: Collaborative Study

Abstract

Abstract The determination of diazinon insecticide in Knox Out 2FM formulation was studied collaboratively by 18 laboratories. Knox Out 2FM is a flowable microencapsulated insecticide formulation containing 23 wt% active ingredient. Analytical samples are first treated by grinding in a tissue grinder and then extracted in situ with acetonitrile. This preparative step breaks the capsules and allows the active ingredient to dissolve in the solvent. Single determinations on each of 2 closely matched samples were made by flame ionization gas-liquid chromatography. The standard deviation by analysts was 0.18 wt% and the coefficient of variation was 0.76%. The combined laboratory and analyst variation gave a standard deviation of 0.59 wt% and a coefficient of variation of 2.49%. The method has been adopted official first action.</jats:p