The 02+ state in 34Si has been populated at the {\sc Ganil/Lise3}
facility through the β-decay of a newly discovered 1+ isomer in
34Al of 26(1) ms half-life. The simultaneous detection of e+e− pairs
allowed the determination of the excitation energy E(02+)=2719(3) keV and
the half-life T1/2=19.4(7) ns, from which an electric monopole strength of
ρ2(E0)=13.0(0.9)×10−3 was deduced. The 21+ state is
observed to decay both to the 01+ ground state and to the newly observed
02+ state (via a 607(2) keV transition) with a ratio
R(21+→01+/21+→02+)=1380(717). Gathering all
information, a weak mixing with the 01+ and a large deformation parameter
of β=0.29(4) are found for the 02+ state, in good agreement with
shell model calculations using a new {\sc sdpf-u-mix} interaction allowing
\textit{np-nh} excitations across the N=20 shell gap.Comment: 5 pages, 3 figures, accepted for publication in Physical Review
Letter