The objective of this work was the development of an onroad
in-vehicle emissions measurement technique
utilizing a relatively new, commercial, portable Fourier
Transform Infra-Red (FTIR) Spectrometer capable of
identifying and measuring (at approximately 3 second
intervals) up to 51 different compounds. The FTIR was
installed in a medium class EURO1 spark ignition
passenger vehicle in order to measure on-road
emissions. The vehicle was also instrumented to allow
the logging of engine speed, road speed, global position,
throttle position, air-fuel ratio, air flow and fuel flow in
addition to engine, exhaust and catalyst temperatures.
This instrumentation allowed the calculation of massbased
emissions from the volume-based concentrations
measured by the FTIR. To validate the FTIR data, the
instrument was used to measure emissions from an
engine subjected to a real-world drive cycle using an AC
dynamometer. Standard analyzers were operated
simultaneously for comparison with the FTIR and the
standard analyzer results showed that most pollutants
(NOx, CO2, CO) were within ~10% of a standard analyzer
during steady state conditions and within 20% during
transients. The exception to this was total HC which was
generally 50% or less than actual total HC, but this was
due to the limited number of hydrocarbons measured by
the FTIR. In addition to the regulated emissions, five
toxic hydrocarbon species were analyzed and found to
be sensitive to cold starts in varying proportions. Finally,
FTIR data was compared to results from a commercially
available on-road measurement system (Horiba OBS-
1000), and there was good agreement
