应用电化学阳极氧化法结合浸渍和退火后处理制备了fE和n共掺杂的TIO2纳米管阵列光催化剂,并用场发射扫描电镜(fESEM)、X射线衍射(Xrd)、X射线光电子能谱(XPS)和俄歇电子能谱(AES)仪对其进行了表征.结果表明,fE、n共掺杂对TIO2纳米管阵列的形貌和结构没有明显影响,fE和n均掺入了TIO2晶格.紫外-可见(uV-VIS)漫反射光谱显示fE和n共掺杂TIO2纳米管阵列的吸收带边较纯TIO2纳米管阵列和单一掺杂TIO2纳米管阵列红移,可见光吸收增强.以可见光催化降解罗丹明b(rHb)考察了材料的光催化活性,fE和n共掺杂TIO2纳米管阵列对rHb的降解速率较纯TIO2纳米管阵列和单一掺杂TIO2纳米管阵列明显提高,证明了fE、n共掺杂产生的协同效应提高了TIO2纳米管阵列在可见光照射下的光催化活性.Fe-N codoped TiO 2 nanotube arrays were fabricated by anodization of Ti,followed by wet immersion and annealing post-treatment.The doped TiO 2 nanotube array photocatalysts were characterized by field-emission scanning electron microscopy(FESEM),X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),and Auger electron spectroscopy(AES).The results indicated that Fe and N dopants had almost no effect on the morphology and structure of TiO 2 nanotube arrays,and that Fe and N were doped into the TiO 2 lattice.UV-Vis diffuse reflectance spectra showed that the absorption band edge of Fe-N codoped TiO 2 nanotube arrays exhibited a red shift compared with that of pure TiO 2 nanotube arrays and Fe-or N-doped TiO 2 nanotube arrays.The photocatalytic activity of Fe-N codoped TiO 2 nanotube arrays was evaluated by their ability to degrade rhodamine B under visible light irradiation.The degradation rate of rhodamine B over Fe-N codoped TiO 2 nanotube arrays was obviously higher than that over pure TiO 2 nanotube arrays and Fe-or N-doped TiO 2 nanotube arrays,which is attributed to the synergistic effect of the Fe and N codopants.国家自然科学基金(51072170;21021002);福建省自然科学基金(2011J01057);国家基础科学人才培养基金(J1030415)资助项目---
