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Improvement of A High PerFormance Amperometric Detector For Flow Through System

Abstract

采用在工作电极(WE)及辅助电极(CE)室衬垫尼龙网布的方法改进了本教研室提出的WE与CE正对面放置型的电流检测[1]。在进样100μl样品(br-),流速2Ml/MIn,检测器电解效率达18.9%,浓度电流线性范围为10-2~10-8MOl/l,重复进样相对标准偏差小于1%。Using a method of padding the working electrode(WE) chamber and complementary electrode (CE) chamber with nylon nets, we improved the Face-to-Face WE/CE type amperometric detector previously developed in our teaching and research section.An injection of a 100 μL Br- sample at a Flow rate of 2 mL/min brings about an electrolytic eFFiciency of 18.9%, a RSD of less than 1 % and a linearity of 10-2-- 10-8 mol/L

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