Study on the Composition and Equilibrium Constant of Metallophthalocyanine/Fullerene Charge TransFer Complexes

Abstract

报道锌酞菁(znPC)和C60在特殊的有机溶剂体系中可形成电荷迁移络合物(CTC),应用紫外可见、荧光、激光拉曼等光谱对CTC进行表征.在不同溶剂中CTC的组成为znPC∶C60=2∶1和1∶1两种,分别测得它们的生成平衡常数(k),CTC显著地增强znPC的光电转移性能.Two types of ZnPc/C 60 charge transFer complexes in special mixed organic solvents are characterized by UV Vis, Fluorescence and laser Raman spectra.The mole ratios of ZnPc/C 60 For CTC are 2∶1 and 1∶1 in diFFerent solvents.The Formation equilibrium constants ( K ) are calculated.The ZnPc C 60 CTC shows the good photoelectrochemistry properties.国家及福建省自然科学基

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