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配位化学中的镜面对称性破缺——纪念配位化学创始人维尔纳首次拆分八面体Co(Ⅲ)络合物100周年
Authors
林丽榕
章慧
Publication date
1 January 2011
Publisher
Abstract
镜面对称性破缺(MIrrOr SyMMETry brEAkIng,简称MSb),是指在一个热力学非平衡体系中非零EE值的状态可以自发地从非手性或消旋态中产生的现象。随着现代X射线衍射技术对晶体结构的阐明以及固体Cd光谱表征方法的日益普及,在配位化学领域中发现的各种MSb现象层出不穷,但是其预测和调控及其发生的某些真实机理仍旧是悬而未决的科学难题。本文介绍与MSb现象(自发拆分和绝对不对称合成)相关的概念、表征方法和实例,并特别探讨了单核或寡聚惟手性金属中心络合物MSb现象的研究及其应用。国家自然科学基金项目(20973136;20773098);国家基础科学人才培养基金项目(J1030415
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Last time updated on 16/06/2016