Syntheses, Structures and Photoluminescences of Ag-aminopyrimidines Coordination Polymers and Pt-Hg & Pd-Hg Heterometallic Diphosphine Complexes

Abstract

本论文主要由银离子与氨基嘧啶衍生物配位聚合物的结构调控;Pt-Hg以及Pd-Hg异核金属双膦配合物的元件组装;基于氟化硼络合卤代二吡咯甲川(BODIPY)衍生物为光敏剂的光解水释氢研究等三大部分构成。 以配位键为主、分子间作用力或主客体相互作用为辅的组装方式赋予了配位聚合物具有可调控性强、结构丰富多样、性质可控空间大等特点。基于此特点,配位聚合物在组装过程中易受到合成条件中一些物理、化学因素的影响,因而通过改变反应的溶剂、反应物料比、配体取代基等因素,可得到结构不同的配位聚合物。在此领域中,探索配位聚合物的组装机制仍为研究的焦点之一。论文第一部分主要由氨基嘧啶衍生物与银离子配位聚合物的结构调...The design and assembly of various coordination polymers are currently of great interest due to the richness of their implications in fluorescence, electricity, magnetism and so on. Coordination polymers were mainly assembled with coordination bonds, and some molecular interactions or host-gurst interactions as well. The corresponding bond energies are relatively low, compared to the covalent bond...学位:理学博士院系专业:化学化工学院化学系_无机化学学号:2052006015320

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