Interaction between Molecule and Metal Probed by Vibrational Spectroscopy——Molecular Adsorption and Reaction on Pt Group Metals Probed by SERS and Charge Transfer between Molecule and Metal Probed by
摘要表面增强拉曼光谱（SERS）经过约三十年的发展，已成为研究界面电化学体系的重要谱学技术。但是，迄今已研究体系大部分局限在金、银、铜等币族金属和一些典型的SERS探针分子，且有关表面增强拉曼散射（SERS）的电荷传递机理仍很不清楚。为了将SERS发展为广泛通用的谱学技术，需要克服和解决以上问题。为此，本论文工作主要分为如下两方面：一．拓宽SERS研究体系。苯、甲苯和乙炔等分子因倾向于在过渡金属电极表面平躺吸附而导致其SERS信号微弱，故有关研究极其有限。通过优化拉曼谱仪的灵敏度和电极表面的粗糙方法，成功地获得这些分子在铂、钌、铑、钯金属上的SERS信号，较系统地研究了它们的电化学吸附行为，从...Abstract With a development of nearly three decades, surface-enhanced Raman spectroscopy(SERS) has become one of the most important in-situ spectroscopies and plays important role in interfacial electrochemistry. However, up to now, most of the research are still limited to three noble metals: Au, Ag and Cu with high SERS activity and the classical SERS probe molecules including pyridine, pyraz...学位：理学博士院系专业：化学化工学院化学系_物理化学(含化学物理)学号：B20022502
