目前商品化的锂离子电池负极主要采用石墨材料。但是石墨负极材料的理论质量比容量(372mAh.g-1)不高,已不能满足不断出现的新的电子产品的要求。科学工作者在对炭材料不断进行改性以提高其容量的同时,也在寻找炭的替代品。Sn金属由于具有较高的理论容量和合适的充放电平台(0.4~0.6VvsLi+/Li)成为研究的重点。然而锡在嵌脱锂过程中体积发生重大的变化(360%),充放电过程中容易脱落和坍塌,造成容量的剧烈衰减。本论文在Sn电极中引入非活性金属、改善电极集流体形貌、在电解液中加入添加剂三个方面入手,着力于提高Sn基合金电极的充放电性能,并且用电化学阻抗方法研究Sn基合金电极嵌脱锂的动力学过程...Nowadays, carbonaceous materials are key anodes for commercial lithium ion batteries, but they can not meet the needs of new electronic devices owing to its low energy density (372 mAh.g-1). Researchers are trying to modify carbon materials to improve their capacity, as well as searching for new carbon alternatives. Sn based metals become research hot for its high theoretical capacity and suitable...学位:理学硕士院系专业:化学化工学院化学系_物理化学(含化学物理)学号:2052006115199