通讯作者地址: Huang, XQ (通讯作者), Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
地址:
1. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
2. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
3. Xiamen Univ, Dept Phys, Xiamen 361005, Peoples R China
电子邮件地址: [email protected] metal films can exhibit quantum size and surface effects that give rise to unique physical and chemical properties(1-7). Metal films containing just a few layers of atoms can be fabricated on substrates using deposition techniques(7), but the production of freestanding ultrathin structures remains a significant challenge. Here we report the facile synthesis of freestanding hexagonal palladium nanosheets that are less than 10 atomic layers thick, using carbon monoxide as a surface confining agent. The as-prepared nanosheets are blue in colour and exhibit a well-defined but tunable surface plasmon resonance peak in the near-infrared region. The combination of photothermal stability and biocompatibility makes palladium nanosheets promising candidates for photothermal therapy. The nanosheets also exhibit electrocatalytic activity for the oxidation of formic acid that is 2.5 times greater than that of commercial palladium black catalyst.NSF of China 20925103
20871100
20721001
20703032
MOST of China 2009CB930703
2011CB932403
Fok Ying Tung Education Foundation 121011
NSF of Fujian 2009J06005
Key Scientific Project of Fujian Province 2009HZ0002-
