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Thiourea-based Receptors for Anion Recognition and Sensing

Abstract

[中文文摘]阴离子识别是超分子化学研究的重要内容之一 ,其关键环节是构筑可识别阴离子的结合受体 ,后者以非共价键力如静电作用、疏水作用、氢键等与阴离子结合。本文详细评述了近 5年来硫脲类阴离子识别受体的设计、结构及其阴离子识别作用的研究进展。[英文文摘] Anion recognition and sensing have been developed into an important research subject in supramolecular chemistry. Noncovalent interactions such as hydrogen bonding , electrostatic interaction , hydrophobic interaction , etc.are the most important binding forces existing in the anion2receptor binding complexes , which forms the basis of designing anion binding receptors. The design , construction and anion recognition and sensing of thiourea2based receptors following mainly multi hydrogen bonding interactions are reviewed. 51 key references were cited to represent the related advances in the past 5 years.国家自然科学基金 (2 0 1 75 0 2 0 );福建省自然科学基金 (D0 2 2 0 0 0 1 )项目

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