通讯作者地址: Huang, RB (通讯作者), Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, 422 S Shimin Rd, Xiamen 361005, Peoples R China
地址:
1. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
2. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
电子邮件地址: [email protected] addition to the traditional Kratschmer-Huffman graphite arc-discharge method, a combustion method has been developed to synthesize fullerenes that defy the isolated pentagon rule (IPR). The C-3v-symmetric (C64H4)-C-#1911, as well as other non-IPR fullerenes such as the possible non-IPR C-60 isomer, have been synthesized as fullerene hydrides in a low-pressure benzene/oxygen diffusion flame. The non-IPR structure of the chromatographically isolated C-64 species was unambiguously identified by its HPLC retention time, UV absorption and mass spectrum by comparison with the reference material C3v-#1911C64H4. The synthesis, isolation and identification of C-3v-(#1911) C64H4, as described in this work, show that this combustion method is successful, is energy efficient and is a promising candidate for the macroscopic synthesis of non-IPR fullerenes. (C) 2009 The Combustion Institute. Published by Elsevier Inc. All rights reserved.Institute of Chemistry, Chinese Academy of Sciences 20571062
20721001
20525103
National Basic Research Program (973 Program) of China 2007CB81530
